2022

A High Throughput Approach for Designing Polymers That Mimic the TRAIL Protein.

Li Z, Han Z, Stenzel MH, Chapman R*; Nano Letters, 2022, https://pubs.acs.org/doi/10.1021/acs.nanolett.1c04469

Delivering hydrophilic peptide inhibitors of heat shock protein 70 into cancer cells

Han Z, McAlpine SR, Chapman R*; Bioorganic Chemistry, 105713

PET-RAFT Enables Efficient and Automated Multiblock Star Synthesis

Foster H, Stenzel MH, Chapman R*; Macromolecules, ASAP

2021

Photo RAFT Polymerization [Book Chapter]

Chapman R, Jung K, Boyer C in RAFT Polymerization: Methods, Synthesis and Applications 1, 611-645

Enabling peristalsis of human colon tumor organoids on microfluidic chips

Fang G, Lu H, Al-Nakashli R, Chapman R, Zhang Y, Ju LA, Lin G, Stenzel MH, Jin D; Biofabrication 14 (1), 015006

The Core–Shell Structure, Not Sugar, Drives the Thermal Stabilization of Single-Enzyme Nanoparticles

Wang Y, Milewska M, Foster H, Chapman R, Stenzel MH; Biomacromolecules 22 (11), 4569-4581

2020

Real time monitoring of peptide delivery in vitro using high payload pH responsive nanogels.

Farazi S, Chen F, Foster H, Boquiren R, McAlpine S, Chapman R*; Polymer Chemistry, 2020, 11, 425-432 [emerging investigators issue]

Polyion Complex-Templated Synthesis of Cross-Linked Single-Enzyme Nanoparticles

Wang Y, Cheng YT, Cao C, Oliver JD, Stenzel MH, Chapman R; Macromolecules, 2020, 5487-5496

Well-defined polymers for non-chemistry laboratories using oxygen tolerant controlled radical polymerization

Li Z, Ganda S, Melodia D, Boyer C, Chapman R; J. Chemical Education, 2020, 97, 2, 549-556.

Tuneable peptide cross-linked nanogels for enzyme-triggered protein delivery

Massi L, Najer A, Chapman R, Spicer CD, Nele V, Che J, Booth MA, Doutch JJ, Stevens MM; J. Mater. Chem. B., 2020, 8894-8907

Polyion Complex Micelles for Protein Delivery Benefit from Flexible Hydrophobic Spacers in the Binding Group

Li K, Chen F, Wang Y, Stenzel MH, Chapman R; Macromol. Rapid Commun., 2020, 200008

Oxidation of graphene with variable defects: alternately symmetrical escape and self-repairing of carbon rings

Zheng P, Zhang X, Duan Y, Yan M, Chapman R, Li H, Jiang Y; Nanoscale, 2020, 12 (18), 10140-10148

Automation of Controlled/Living Radical Polymerization

Tamasi M, Kosuri S, DiStefano J, Chapman R, Gormley AJ; Adv. Intelligent Systems, 2020, 1900126

2019

A Dual Wavelength Polymerization and Bioconjugation Strategy for High Throughput Synthesis of Multivalent Ligands

Li Z, Kosuri S, Foster H, Cohen J, Jumeaux C, Stevens MM, Chapman R* Gormley AJ*; J. Am. Chem. Soc., 2019, 141, 50, 19823-19830

Polymer mediated transport of the Hsp90 inhibitor LB76, a polar cyclic peptide, produces an Hsp90 cellular phenotype

Rahimi M, Foster H, Farazi S, Chapman R*, McAlpine S*; Chemical Communications, 2019, 55, 4515-4518.

All wrapped up: Stabilization of enzymes within single enzyme nanoparticles

Chapman R*, Stenzel MH*; J. Am. Chem. Soc., 2019, 141, 7, 2754-2769

Living in the Fast Lane—High Throughput Controlled/Living Radical Polymerization

Oliver S, Zhao L, Gormley AJ, Chapman R, Boyer C; Macromolecules, 2019, 52(1), 3-23.

2018

Up in the Air: Oxygen Tolerance in Controlled/Living Radical Polymerization

Yeow J, Gormley AJ, Chapman R, Boyer C; Chemical Society Reviews, 2018, 47, 4357-4387

An oxygen tolerant PET-RAFT polymerisation for screening structure-activity relationships

Gormley AJ, Yeow J, Ng G, Conway O, Boyer C, Chapman R*; Angewandte Chemie Int. Ed., 2018, 57 (6), 1557-1562

A Self-Reporting Photocatalyst for Online Fluorescence Monitoring of High Throughput RAFT Polymerization

Yeow J, Joshi S, Chapman R, Boyer C; Angewandte Chemie Int. Ed., 2018, 47, 4235-4666

Pushing the Limits of High Throughput PET-RAFT Polymerization

Ng G, Yeow J, Chapman R, Isahak N, Wolvetang E, Cooper-White JJ, Boyer C; Macromolecules, 2018, 51 (19), 7600-7607

Polymeric Nanocapsules for Enzyme Stabilization in Organic Solvents

Ishizuka F, Chapman R, Kuchel RP, Coureault M, Zetterlund PB, Stenzel MH; Macromolecules, 2018, 51 (2), 438–446

A Low Friction, Biphasic and Boundary Lubricating Hydrogel for Cartilage Replacement

Milner P, Parkes M, Putzer JL, Chapman R, Stevens MM, Cann P, Jeffers J; Acta Biomaterialia, 2018, 65, 102-111

2017

Controlled poly(olefin)s via decarboxylation of poly(acrylic acid)

Chapman R*, Melodia D, Qu JB, Stenzel MH, Polymer Chemistry, 2017, 8, 6636-6643

Swollen Micelles for the Preparation of Gated, Squeezable, pH-Responsive Drug Carriers

Qu JB, Chapman R, Chen F, Lu H, Stenzel MH; ACS Adv. Mater. Int. , 2017, 9, 13865-13874

Oxygen tolerant photopolymerization for ultralow volumes

Yeow J, Chapman R, Xu J, Boyer C; Polymer Chemistry, 2017, 8, 5012-5022

2016

Combinatorial Low-Volume Synthesis of Well-Defined Polymers by Enzyme Degassing

Chapman R, Gormley AJ, Stenzel MH, Stevens MM; Angewandte Chemie Int. Ed., 2016, 55, 4500 - 4503

Point of care testing of phospholipase A2 group IIA for serological diagnosis of rheumatoid arthritis

Liu NJ, Chapman R, Lin Y, Mmesi J, Bentham A, Tyreman M, Abraham S, Stevens MM; Nanoscale, 2016, 8, 4482

Phospholipase A2 as a point of care alternative to serum amylase and pancreatic lipase

Liu NJ, Chapman R, Lin Y, Bentham A, Tyreman M, Philips N, Khan SA, Stevens MM; Nanoscale, 2016, 8, 11834 - 11839

2015

Dual functional scaffold with opposing cell adhesive and anti-adhesive surfaces generated by flexible usage of surface initiated polymer growth and peptide functionalization

Harrison RH, Steele JAM, Chapman R, Gormley AJ, Chow LW, Mahat M, Podhorska L, Hettiaratchy SP, Dunlop IE, Stevens MM; Adv. Functional Mater. 2015, 25, 5748. [Cover article]

Synthesis and self-assembly of temperature-responsive copolymers based on N-vinylpyrrolidone and triethylene glycol methacrylate

Jumeaux C, Chapman R, Chandrawati R, Stevens MM; Polymer Chemistry, 2015, 6, 4116

Integrative self-assembly of graphene quantum dot and biopolymer into a versatile biosensing toolkit

Lin Y, Chapman R, Stevens MM; Adv. Functional Mater. 2015, 25, 3183.

Multivalent Nanoparticle Networks Enable Point-of-Care Detection of Human Phospholipase-A2 in Serum

Chapman R, Lin Y, Burnapp M, Bentham A, Hillier D, Zabron A, Khan S, Tyreman M, Stevens MM; ACS Nano, 2015, 9, 2565 - 2573

2014

Highly controlled open vessel RAFT polymerizations by enzyme degassing

Chapman R, Gormley AJ, Herpoldt KL, Stevens MM; Macromolecules, 2014, 47, 8541

Polymerization Amplified Detection for Nanoparticle-Based Biosensing

Gormley AJ, Chapman R, Stevens MM; Nano Letters, 2014, 14, 6368-6373

Label-free multimodal protease detection based on protein/perylene dye coassembly and enzyme-triggered disassembly

Lin Y, Chapman R, Stevens MM; Analytical Chemistry, 2014, 86, 6410.

Drug conjugation to cyclic Peptide-polymer self-assembling nanotubes

Blunden BM, Chapman R, Danial M, Lu H, Jolliffe KA, Perrier S, Stenzel MH; Chemistry - A European Journal, 2014, 20, 12745.

2013

Thermoresponsive cyclic peptide – poly(2-ethyl-2-oxazoline) conjugate nanotubes

Chapman R, Bouten P, Hoogenboom R, Jolliffe KA, Perrier S; Chemical Communications, 2013, 49, 6522.

Structure elucidation and control of cyclic peptide-derived nanotube assemblies in solution

Chapman R, Koh ML, Warr GG, Jolliffe KA, Perrier S; Chemical Science, 2013, 4, 2581 - 2581

Multi-shell Soft Nanotubes from Cyclic Peptide Templates

Chapman R, Jolliffe KA, Perrier S; Advanced Materials, 2013, 25, 1170 - 1172

Water-Soluble and pH-Responsive Polymeric Nanotubes from Cyclic Peptide Templates

Chapman R, Warr GG, Jolliffe KA, Perrier S; Chemistry - A European Journal, 2013, 19, 1955.

2012

Design and properties of functional nanotubes from the self-assembly of cyclic peptide templates

Chapman R, Danial M, Koh ML, Jolliffe KA, Perrier S; Chemical Society Reviews, 2012, 41, 6023 - 6023

Synthesis and Immunological Evaluation of Self-Assembling and Self-Adjuvanting Tricomponent Glycopeptide Cancer-Vaccine Candidates

Wilkinson BL, Day S, Chapman R, Perrier S, Apostolopoulos V, Payne RJ; Chemistry - A European Journal, 2012, 18, 16540.

Thioketone-Mediated Polymerization with Dithiobenzoates: Proof for the Existence of Stable Radical Intermediates in RAFT Polymerization

Junkers T, Delaittre G, Chapman R, Günzler F, Chernikova E, Barner-Kowollik C; Macromolecular Rapid Communications, 2012, 33, 984.

Pushing the limits of copper mediated azide-alkyne cycloaddition (CuAAC) to conjugate polymeric chains to cyclic peptides

Poon CK, Chapman R, Jolliffe KA, Perrier S; Polymer Chemistry, 2012, 3, 1820.

2011

Modular design for the controlled production of polymeric nanotubes from polymer/peptide conjugates

Chapman R, Jolliffe KA, Perrier S; Polymer Chemistry, 2011, 2, 1956 - 1956

Synthetic Strategies for the Design of Peptide / Polymer Conjugates

Dehn S, Chapman R, Jolliffe KA, Perrier S; Polymer Reviews, 2011, 51, 214.

Synthesis of Self-assembling Cyclic Peptide-polymer Conjugates using Click Chemistry

Chapman R, Jolliffe KA, Perrier S; Aust. J. Chem., 2010, 63 (8), 1169-1172.